Synthesis and structure of a dimetallated buckybowl: coordination of one [Cp*Ru]+ unit to each side of corannulene.
نویسندگان
چکیده
منابع مشابه
SYNTHESIS, X-RAY CRYSTAL STRUCTURE AND IR STUDY OF NEW TRINUCLEAR, BASE CARBOXSYLATE COMPLEX OF [Cu3O(OAc)6(H2O)3]Cl.CH3OH.6H2O
The synthesis of [Cu3O(OAc)6(H2O)3]Cl.CH3OH.6H2O is described. The X-ray crystallographic study of thecomplex revealed an isosceles triangle of copper atoms with a triply bridging oxo atom nearly in the plane of thetriangle. The coordination sphere around each metal center is close to distorted octahedral and the central{Cu3(μ3-O)} core is planar. Every two copper atoms were connected to each o...
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The supramolecular dimerization of tetraanionic corannulene is utilized as a self-assembly motif for the construction of highly charged, buckybowl-based supramolecular oligomers. Oligomers of up to 7 units (3900 g mol(-1)) of reduced dicorannulenic monomers are identified and characterized by various NMR techniques, and the reversibility of their assembly is established through the concentratio...
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ورودعنوان ژورنال:
- Angewandte Chemie
دوره 43 34 شماره
صفحات -
تاریخ انتشار 2004